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Detection·Sensitify Studio

Peak finding

Locate peaks in voltammetric scans and report position, height, area, and full width at half maximum.

A voltammetric peak carries two pieces of information. Its position tells you what the species is; its height tells you how much of it is there. Peak finding in Studio extracts both in one pass.

The same routine works on CV, DPV, and SWV, on scans with a single clean peak or on scans with half a dozen overlapping features.

When to use it

How it works

Studio subtracts a locally fitted baseline, then scans the result for local maxima that pass a prominence threshold. Each candidate is fitted with a symmetric lineshape to refine position, height, and FWHM.

For CVs specifically, both anodic and cathodic peaks are detected. Peak separation (ΔEp) and current ratio (ipa / ipc) are reported automatically.

Sensitify Studio
Peak finding in Sensitify Studio

Parameters you set

Baseline mode

Typical: Linear

Linear, tangent, or polynomial baseline under the peak. Linear for well-separated peaks, tangent for shoulders, polynomial for sloping backgrounds.

Prominence threshold

Typical: 3× baseline noise

Minimum peak height above baseline before a feature is counted. Raise to suppress noise, lower to catch small peaks.

Search window

Potential range in which to look. Leave empty to search the full scan.

Lineshape

Typical: Gaussian

Gaussian, Lorentzian, or asymmetric. Used to refine width and area. Gaussian covers most diffusive voltammograms.

Example

Walkthrough

Quantify dopamine from a DPV calibration series

  1. 1Load the DPV scans (five concentrations) into Studio.
  2. 2Analyse → Find peaks. Set Prominence to 3× noise, Baseline to Linear.
  3. 3Studio reports Ep, ip, area, and FWHM for each scan.
  4. 4Plot ip versus concentration. A linear fit yields the calibration slope and R².
  5. 5Compute limit of detection as 3σ / slope using the reported baseline noise.

Result

Calibration slope, intercept, R², and a limit of detection calculated from the measured noise. Every number traces back to the raw scan.

In Sensitify Studio

Find peaks sits next to the scan plot in Sensitify Studio. Run it on a single scan or apply it to a whole batch. Detected peaks overlay directly on the data and the parameter table updates live as you adjust the prominence threshold.

Step-by-step in docs

Find peaks